Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution

By Neta, Pedatsur

Book Id: WPLBN0000659568
Format Type: PDF eBook:
File Size: 19.27 MB
Reproduction Date: 2005

Title:	Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
Author:	Neta, Pedatsur
Volume:
Language:	English
Subject:	Technology., Reference materials, Technology and literature
Collections:	Techonology eBook Collection
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Citation APA MLA Chicago Neta, B. P. (n.d.). Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution. Retrieved from http://self.gutenberg.org/

Description
Technical Reference Publication

Excerpt
Introduction: Since the publication of the original compilation on this topic in 1979' the number of measured rate constants for reactions of inorganic radicals has more than doubled. Because of the importance of these radicals as basic chemical species, in the study of electron transfer theory, as well as in atmospheric and industrial processes, it is necessary to update the compilation. The present tables include the rate constants presented in the original compilation, with some revisions where appropriate, and rate constants published through mid 1987. The tables cover those radicals given in the original version as well as several...

Table of Contents
Contents 1. Introduction . . . . . . . . . . . . . . . . .. . . . . . . . . . 1028 2. General Methods . . . . . . . . . . . . . . . . . . . . . . . 1028 3. Radical Production and Properties . . . . . . . . 1028 3.1. Carbon Dioxide Radical Anion . . . . . . 1028 3.2. Carbonate Radical . . . . . . . . . . . . . . . . . 1029 3.3. Ozone . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1029 3.4. Azide Radical . . . . . . . . . . . . . . . . . . . . . 1029 3.5. Amino Radical . . . . . . . . . . . . . . . . . . . . 1030 3.6. Nitrogen Dioxide Radical . . . . . . . . . . 1030 3.7. Nitrogen Trioxide Radical . . . . . . . . . . 1030 3.8. Phosphite Radical . . . . . . . . . . . . . . . . . 103 1 3.9. Phosphate Radical . . . . . . . . . . . . . . . . . 103 1 3.10. Sulfur Dioxide Radical Anion . . . . . . . 103 1 3.1 1. Sulfite Radical . . . . . . . . . . . . . . . . . . . . 1032 3.12. Sulfate Radical . . . . . . . . . . . . . . . . . . . . 1032 3.13. Peroxomonosulfate Radical . . . . . . . . . 1033 3.14. Selenite Radical . . . . . . . . . . . . . . . . . . . 1033 3.15. Dill~io~ya~lalRatd:i cal . . . . . . . . . . . . . . 1034 3.16. Dihalogen Radical Anions . . . . . . . . . . 1034 3.17. Chlorine Dioxide . . . . . . . . . . . . . . . . . . 1034 3.18. Bromine Dioxide . . . . . . . . . . . . . . . . . . 1035 4. Comparison of the Reactivities of Various Radicals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1035 4.1. Oxidizing Radicals . . . . . . . . . . . . . . . . . 1035 4.2. Reducing Radicals . . . . . . . . . . . . . . . . . 1035 5. Arrangement of Tables 3-29 . . . . . . . . . . . . . . 1036 6. List of Abbreviations and Symbols . . . . . . . . 1036 7. Acknowledgments .. . ... .. .. . . .. . . . . . . . 1037 8. References to Text . . . . . . . . . . . . . . . . . . . . . . 1037 9. References to Tables 3-29 . . . . . . . . . . . . . . . . 1229 10. Indexes ................................ 1248 10.1. Molecular Formula Index . . . . . . . . . . 1248 10.2. Chemical Name Index . . . . . . . . . . . . . . 1262 List of Tables 1. Comparison of the reactivity of oxidizing radicals with inorganic and organic compounds ................................ 1039 2. Comparison of the reactivity of reducing radicals with inorganic and organic compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1040 3. Rate constants for the carbon dioxide radical anion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1041 4. Rate constants for the carbonate radical . . . 1065 5. Rate constants for ozone . . . . . . . . . . . . . . . . . 1080 6. Ralc cu~~sliu~flusr Lhe azide radical . . . . . . . 11 0 1 7. Rate constants for the amino radical . . . . . . 11 10 8. Rate constants for nitrogen dioxide . . . . . . . 11 12 9. Rate constants for nitrogen trioxide . . . . . . . 1 1 16 10. Rate constants for miscellaneous nitrogencontaining radicals . . . . . . . . . . . . . . . . . . . . . . 1 1 19 11. Rate constants for phosphite radicals . . . . . . 1121 12. Rate constants for phosphate radicals . . . . . . 11 22 13. Rate constants for the sulfur dioxide radical anion .................................1 128 14. Rate constants for the sulfite radical . . . . . . . 1142 15. Rate constants for the sulfate radical . . . . . . 1146 16. Rate constants for the peroxomonosulfate radical ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 160 01988 by the U. S. Secretary of Commerce on behalf of the United States. This copyright is assigned to the American Institute of Physics 17' Rate constants for lfurand the American Chemical Society. containing radicals . . . . . . . . . . . . . . . . . . . . . . 1 162 Reprints available from ACS; see Reprints Lit at back of issue. 18. Rate constants for the selenite radical . . . . . 1164 0047-2689/88/031027-258/$21.00 1027 J. Phys. Chem. Ref. Data, Vol. 17, No. 3,1988